We consider the existence of positive solutions for the following fractional Schrödinger-Poisson system
$ \begin{equation*} \begin{cases} \varepsilon^{2s}(-\Delta)^{s}u+V(x)u+\phi(x)u = K(x)f(u)+|u|^{2_{s}^{*}-2}u, \ \ & x\in \mathbb{R} ^3, \\ \varepsilon^{2s}(-\Delta)^{s}\phi = u^{2}, \ \ & x \in \mathbb{R} ^3, \end{cases} \end{equation*} $
where $ s \in (\frac{3}{4}, 1) $, $ \varepsilon $ is a small and positive parameter, $ V $ and $ K $ are nonnegative potential functions. $ 2_{s}^{*} $ is the critical exponent with respect to fractional Sobolev embedding theorem. Under some suitable conditions on the nonlinearity $ f $ and potential functions $ V $ and $ K $, we prove that for $ \varepsilon $ small, the system has a positive ground state solution concentrating around a concrete set related to $ V $ and $ K $. This result generalizes the result for fractional Schrödinger-Poisson system with subcritical exponent by Yu et al. [
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