We consider a class of random mechanical systems called random billiards to study the problem of quantifying the irreversibility of nonequilibrium macroscopic systems. In a random billiard model, a point particle evolves by free motion through the interior of a spatial domain, and reflects according to a reflection operator, specified in the model by a Markov transition kernel, upon collision with the boundary of the domain. We derive a formula for entropy production rate that applies to a general class of random billiard systems. This formula establishes a relation between the purely mathematical concept of entropy production rate and textbook thermodynamic entropy, recovering in particular Clausius' formulation of the second law of thermodynamics. We also study an explicit class of examples whose reflection operator, referred to as the Maxwell-Smoluchowski thermostat, models systems with boundary thermostats kept at possibly different temperatures. We prove that, under certain mild regularity conditions, the class of models are uniformly ergodic Markov chains and derive formulas for the stationary distribution and entropy production rate in terms of geometric and thermodynamic parameters.
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Figure 6. Entropy production for a billiard system whose billiard domain is formed by the union of two discs of equal radius $ r $ whose centers are $ a $ units apart. The ratio parameter is $ a/2r $ and the number above each graph is the temperature difference $ T_2-T_1 $. The vertical bars indicate 95% confidence intervals
Figure 8. When $ F = 0 $ the conveyor belt steadily drifts counterclockwise when $ T_h-T_c>0 $, and clockwise when the temperatures are reversed. The temperatures for the top $ 4 $ graphs are $ T_c = 1 $ and $ T_h = 1, 10, 25, 50 $, and $ T_c, T_h $ are reversed for the $ 3 $ lower graphs. The inset is the same as the graph for $ T_c = T_h = 1 $ but in a finer scale so that its stochastic character is more clearly apparent
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Depiction of some of the vectors appearing in the proof of Proposition 5
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