Classical gradient systems have a linear relation between rates and driving forces. In generalized gradient systems we allow for arbitrary relations derived from general non-quadratic dissipation potentials. This paper describes two natural origins for these structures.
A first microscopic origin of generalized gradient structures is given by the theory of large-deviation principles. While Markovian diffusion processes lead to classical gradient structures, Poissonian jump processes give rise to cosh-type dissipation potentials.
A second origin arises via a new form of convergence, that we call EDP-convergence. Even when starting with classical gradient systems, where the dissipation potential is a quadratic functional of the rate, we may obtain a generalized gradient system in the evolutionary $Γ$-limit. As examples we treat (ⅰ) the limit of a diffusion equation having a thin layer of low diffusivity, which leads to a membrane model, and (ⅱ) the limit of diffusion over a high barrier, which gives a reaction-diffusion system.
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For reversible, time-continuous Markov processes the large-deviation principle (LPD) of Section 2.4 provides a (generalized) gradient structure. This mapping commutes with taking the limit
Left: Three-state Markov process with high rate of leaving state 2. Right: The limit for
The potential